She’s no stranger to the glitz and glamour of industry events, and earlier tonight (September 13) Leighton Meester was spotted arriving at the 2009 MTV Video Music Awards. The “Gossip Girl” hottie looked super sexy as she meandered inside Radio City Music Hall in a skimpy silver minidress teamed with a pair of futuristic white..silver heels. Once the shindig began, Miss Meester joined a juiced-up Jack Black to present one of the night’s many illustrious awards. Leighton joins a bevy of young Hollywood stars at the VMA’s including Robert Pattinson, Taylor Lautner, and Taylor Swift.